Preheat oven to 350 degrees, and spray a 9x13 baking pan with cooking spray. Combine melted butter, sugar, vanilla, and eggs, and mix well. In a second bowl, mix together flour, cocoa, baking powder and salt. Gradually add to the butter mixture, beating well until blended. Spread evenly into your prepared pan. Bake 20-25 minutes, or until brownie begins to pull away from edges and a toothpick comes out clean. Do not overbake!! Once brownies are cool, frost with Chocolate Buttercream Frosting.